Refrigerants for the 21st Century
1. Food Preservation

Prehistoric men and women, when not fighting off their enemies or predators, spent most of their waking hours hunting and foraging for food. They had little choice since bacteria and molds would rapidly spoil the food, once obtained, especially in the warmer climates.

With time, they learned how to prolong the utility of their food supply by drying, smoking, boiling, pickling or salting it. However, these techniques often caused changes in taste and texture, and probably reduced the food's nutritional value.

Those members of that ancient society living in the more temperate climates probably noticed that food did not spoil so quickly during cold weather, and that frozen food remained edible for quite a long time. Food storage in caves and cold cellars could be used effectively as the temperature warmed.

 


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The situation did not improve much through the ages until the mid-19th century. Techniques of preserving ice by crude forms of insulation, such as straw, and shipping it to warmer climates were developed. Ice boxes, containing blocks of ice, were still in use in the 1940s.
The ice was delivered door-to-door by wagons, often drawn by a horse. Often, in poorer communities, it was not uncommon to see small cabinets on the outside of kitchen windows where food was stored during the winter months.

This ChemCases.com discussion shows how engineering and chemistry, working together, led to mechanical refrigeration as a means to preserve food and other perishable materials, with the additional benefit of making work more efficient and living more comfortable through air conditioning. Finally, it shows how, based on chemical structure-reactivity relationships, new refrigerants have been selected to be compatible with the earth's protective ozone layer.

Video about the Ice Box, 1928

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A 1902 Patent Issued for an Overflow Alarm for an Ice Box Water Pan


Concept Map for this ChemCase

Fluorocarbon Alternatives
Case Study: Ozone Layer Degradation

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2. Mechanical Refrigeration
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Principal Investigator Laurence Peterson; Project Director Matthew Hermes;
Author of this module William Gumprecht.