| Some
Concepts for Consideration: we see of materials to
postulate microscopic phenomena at the atomic and
molecular scale.
For
example, we studied the properties of liquids. We
saw that water boils at a very high temperature
for a substance with a molecular weight of 18,
thus we postulate that some forces we call
hydrogen bonds hold individual water molecules
together.
Conversly,
we use the information we get at the molecular
level to explain what we actually
experience. For example, we looked
at the crystal structure of ice as determined by
x-ray analysis. We could calculate that
individual water molecules in ice were held far
enough apart in the crystal to make the overall
density of crystalline ice less
than water. The crystal structure explains
why ice floats on water.
In studying
chemistry, we are forced to represent both this
microscopic realm and
our tangible surroundings through imperfect
symbols.
Our
representations always lack some precision in
expressing reality.
For
example, the symbol H2O as the
structure of water gives us the ratio of hydrogen
to oxygen, but fails to tell us the oxygen is
bonded to each of the hydrogens and the angle of
the bonds between the three atoms is 109o.
Warning!
Acid-base
chemistry
depends upon an understanding of chemical
equilibrium. But our representations of
equilibrium are generally flawed by the fact that
when we DO anything to a system at equilibrium,
we disturb the system and it is no longer in
equilibrium. For example, we will
do many calculations in chemistry expressing
equilibrium conditions after one or more
conditions has changed. But in most real
world systems, true equilibrium conditions are
never reached since systems are influenced by
ever-changing conditions.
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